Beilstein J. Org. Chem.2013,9, 342–391, doi:10.3762/bjoc.9.39
chemical nature that is important for the occurrence of spin crossover will be made. A subsequent section describes the molecular consequences of spin crossover and the variety of physicaltechniques usually applied for their characterization. The effects of light irradiation (LIESST) and application of
phenomenon encompasses mono-, oligo- and polynuclear iron(II) complexes and cages, polymeric 1D, 2D and 3D systems, nanomaterials, and polyfunctional materials that combine spin crossover with another physical or chemical property.
Keywords: cages; iron(II) coordination compounds; physicaltechniques
positive muons μ+ implanted into a sample act as probes of local magnetization. Information about magnetic fluctuations is obtained in a time window covering the range of 10−9–10−5 s, which complements the time windows of other physicaltechniques for studying dynamic phenomena [143][144][145][146][147
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Graphical Abstract
Figure 1:
Change of electron distribution between HS and LS states of an octahedral iron(II) coordination com...